CATALYSIS

ALD can be used effectively for catalysis in various applications. Usually, catalytic materials are very thin and often on porous substrates, a familiar territory of ALD. This thesis discusses ALD on catalyst supports and reviews some catalytic materials grown with ALD such as CrOx, VOx, Co, Ni, WOx, TiO2, LaOx, YOx, CeO, etc. This thesis discusses ALD of noble metals for a variety of applications, including for catalysis.

Nanostructured catalytic membrane structures have been fabricated by a combination of anodic aluminum oxidation and ALD for use as platforms for the synthesis of highly uniform heterogeneous catalysts. The ALD method makes it possible to control pore diameters on the Angstrom scale even when the overall pore diameter is 10’s to 100’s of nanometers. Vanadia-coated membranes have been tested for the catalytic oxidative dehydrogenation of cyclohexane and show improved selectivity at the same conversion compared to conventional powdered alumina supported vanadia catalysts.

We expect Pt ALD to be a great replacement of conventional noble metal washcoats for automobile catalytic converters and are actively working on this application. Cambridge NanoTech ALD systems can successfully grow the noble metals and metal-oxide catalytic materials, take a look at our search page or consult with us for your specific application.